Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Sasaki, Yuji; Nakase, Masahiko*; Kaneko, Masashi; Kobayashi, Toru; Takeshita, Kenji*; Matsumiya, Masahiko*
Analytical Sciences, 5 Pages, 2023/00
Times Cited Count：0 Percentile：0(Chemistry, Analytical)We conducted three field researches on Ru-extraction, XANES, and DFT-calculation. The order of the distribution ratio, D(Ru), from acid, HCl 
H
SO
HNO
HClO, by MIDOA is studied by XANES spectra, which indicates the valency change of Ru in HCl media and supports the ion pairing extraction of anionic Ru ion and cationic MIDOA. The same extractant trend, NTAamide MIDOA IDOA, due to D values as the energy gap of HOMO and LUMO could be found by DFT calculation, which suggests that the reaction heat has a positive correlation with extractability for extractant.
metallized by hydrogen irradiationIto, Takashi
Meson, (56), p.21 - 26, 2022/09
no abstracts in English
Tang, J.*; Seo, O.*; Rivera Rocabado, D. S.*; Koitaya, Takanori*; Yamamoto, Susumu*; Namba, Yusuke*; Song, C.*; Kim, J.*; Yoshigoe, Akitaka; Koyama, Michihisa*; et al.
Applied Surface Science, 587, p.152797_1 - 152797_8, 2022/06
Times Cited Count：7 Percentile：75.56(Chemistry, Physical)The hydrogen absorption and diffusion mechanisms on cube-shaped Pd nanoparticles (NPs) which are important hydrogen-storage materials were studied using X-ray photoelectron spectroscopy and DFT calculations. In the surface region, hydrogen absorption showed almost similar behavior regardless of the NPs size. It was found that the octahedral sites are more favorable than the tetrahedral sites for hydrogen occupation. We also clarified that the hydrogen atoms absorbing on the smaller-sized Pd NPs diffuse to the subsurface more actively because of the weakened Pd-H bond by the surface disordering, which plays an important role in hydrogen adsorption at a low H
pressure.
Miyazaki, Yasunori; Watanabe, So; Sano, Yuichi; Kofuji, Hirohide; Takeuchi, Masayuki; Ishigami, Ryoya*; Koka, Masashi*; Sato, Takahiro*
no journal, ,
no abstracts in English
Kinoshita, Ryoma; Sasaki, Yuji; Kaneko, Masashi; Matsumiya, Masahiko*; Shinoku, Kota*; Shiroishi, Hidenobu*
no journal, ,
Many metal ions are stable in hydrochloric acid solutions as anionic species; diamidic-extractants containing tertiary amino nitrogen atom, such as NTAamide (hexaalkyl-nitrilotriacetamide), are normally protonated in acidic solutions and become cationic extractants. In this study, the ion-pair extraction reactions of metal chloride anions with cationic NTAamide(C6) extractant were investigated. In addition, we attempted to predict the distribution ratio by combining the stability constants of metal chloride complexes and DFT calculations, and compared the results with experimental values.
